Physico-chemical characteristics and biodegradability of primary effluent and particulate matter removed by microscreens.

In this study, the physical, chemical, and biological characteristics of raw wastewater were compared with the liquid and solid streams generated by a primary clarifier (PC), a rotating belt filter (RBF, 350 µm), and a drum filter (DF, 60 µm) and series (SER) combination of an RBF with a PC or a DF using pilot-scale primary treatment units. The RBF removed about 36% of the influent total suspended solids. The DF and PC yielded an influent total suspended solid removal of 47% to 55% in both individual (parallel) and SER configurations. The size fractionation and chemical characterizations of the liquid fractions indicated a significant change in the wastewater composition in both filter configurations with no variation in the biodegradability of liquid fractions. The solids recovered by RBF had a higher total solids (TS) concentration and a higher volatile solids (VS) content (0.92 g VS/g TS) than that of DF and PC treatments (0.58 to 0.84 g VS/g TS). DF and PC sludge demonstrated a higher biodegradability rate (k1 ; 0.11 d-1 < k1 < 0.20 d-1 ) than solids recovered by RBF (0.09 d-1 ). The retained solids in the SER configuration demonstrated a significantly lower theoretical biochemical methane potential than the parallel configuration, likely due to the presence of smaller particles with a significantly higher ratio of particulate chemical oxygen demand over volatile suspended solids (1.86 to 2.40 g chemical oxygen demand/g volatile suspended solids). These results indicated that the physical, chemical, and biological characteristics of liquid and solids from different filter configurations are required to determine design criteria to upgrade or retrofit water resource recovery facilities using an RBF or a DF. PRACTITIONER POINTS: A rotating belt filter (RBF) removed less solids than a drum filter (DF) or a primary clarifier (PC). A series configuration of an RBF with either a DF or PC resulted in an effluent with a lower proportion of slowly biodegradable organic matter than in a parallel configuration. Solids from an RBF, a DF, or a PC had similar theoretical biochemical methane potential.

Enhancing sludge dewaterability and phosphate removal through a novel chemical dosing strategy using ferric chloride and hydrogen peroxide.

In this study, we replicated full-scale centrifuge dewatering utilized in water resource recovery facilities (WRRFs) by using the Higgins modified centrifuge technique and demonstrated that analogous cake solid content and centrate suspended solids were attainable while applying a lower polymer dosage. Furthermore, we demonstrated a dramatic reduction in the concentration of phosphate (P) in anaerobically digested sludge (ADS) under various reaction conditions. H2 O2 was employed to convert embedded iron in ADS, in the form of FeS, to Fe (II) and Fe (III), which subsequently reacted to precipitate phosphate compounds, dropping the in situ P concentration by nearly 50%. Adding ferric chloride (220 mg/L) in ADS enhanced the P-removal to more than 80%. Finally, simultaneous dosing of Fe and H2 O2 boosted P-removal efficiency to higher than 90%. The role of Fe in strengthening the flocs and increasing the dewaterability was also substantiated by demonstrating a 2% growth in the cake solid content when ADS was conditioned with Fe + H2 O2 preceding polymer treatment. The outcome of this work confirms that a deeper understanding of centrifuge operational parameters and physico-chemical properties of wastewater sludge would result in improved performance of municipal WRRFs. PRACTITIONER POINTS: Dosing hydrogen peroxide effectively converted iron embedded in sludge from Fe (II) to Fe (III). Simultaneous dosing of iron and hydrogen peroxide boosted P removal efficiency. The role of iron in strengthening flocs and enhancing dewaterability was observed, as it increased cake solid content in centrifuged sludge. An advanced bench-scale test protocol was employed to optimize polymer dose, simultaneously reducing polymer consumption while maximizing cake solid content and centrate quality.

Native defects determine phase-dependent photoluminescence behavior of Eu(2+) and Eu(3+) in In2O3 nanocrystals.

We demonstrate the coexistence of Eu(2+) and Eu(3+) in corundum and bixbyite-type colloidal In2O3 nanocrystals. The emission properties of dopants in both oxidation states are determined by their interaction with native defects, and are dramatically different in the two nanocrystal phases. This difference arises from the smaller nanocrystal size and higher defect density in metastable corundum-type nanocrystals.